Amy Cavanaugh included a short section on Puerto Rican plans in the Coverage and Nondicrimination Anser Book (2nd edition)
(Heck she 'suckered' me into editing much of the book, I should know!)
According to her comments, filing for a determination letter is required under the Puerto Rico Code in order for the plan to receive favorable tax treatment. Form letters for requests are available on the Hacienda Web site
http://www.hacienda.prstar.net.
(web site is in Spanish only)
Hacienda is the Puerto Rico Treasury
good luck, amigo!